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Zinc dialkyl dithiosphosphate
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RC  



Joined: 25 Mar 2007
Posts: 2637
Location: Australia

PostPosted: Sun Feb 08, 2009 2:35 am    Post subject: Zinc dialkyl dithiosphosphate Reply with quote

Or commonly abbreviated to ZDDP, is an oil additive reputed to be the best at reducing metal to metal friction, wear and galling especially on flat tappets (followers) and camshafts, such as those in all 924`s, 2.0L, turbo, and 924S 2.5L.

Critical for the reliability and longevity of our engines valvetrain it has been the optimal preferred additive by oil manufacturers over the years. Still is, however due to the progressively recent EPA regulations affecting OEM producers regarding catalytic converter service life, this vital component has been reduced successively over recent years.

An accepted level of ZDDP was 1400 PPM (0.14%) at the time our cars were built, and appropriate grade oil was indeed specified by Porsche, API SE or better. Depends on the definition of better. Modern oil is now API SM specification. The ZDDP content is regulated at < 800 PPM (0.08%). Better for marginally extended cat life, debatable improvement in fuel economy, and dramatically better at chewing up our cams and followers. Practically all modern engines manufactured to use this grade are twin cam multi valve, with quite low spring pressures and usually running roller lifters or followers.

How many members have experienced cam and lifter problems in recent years? Very interested to hear from those who may have had their car for many years, especially from new. For the more mature members, can you recall many valve train failures in the early days, 70`s and 80`s? on Porsches or Chevvies if it comes to that. Or is it a predominantly modern phenomenon?

Personally believe so as do numerous engine builders, cam manufacturers and poor owners. Keen to hear others experiences, good or bad, not necessarily opinions on oil brand A,B or X rather on zinc dialkyl dithiosphosphate and its relative content.


http://www.lnengineering.com/oil.html#Z13

http://streetrodder.automotive.com/72322/0803sr-modern-engine-oil/questions.html

http://streetrodder.automotive.com/72322/0803sr-modern-engine-oil/questions.html
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Min  



Joined: 04 Nov 2002
Posts: 2368
Location: Vernon, British Columbia, Canada

PostPosted: Sun Feb 08, 2009 9:28 am    Post subject: Reply with quote

This perked my interest, is there a additive we can just add to our oil to give us higher levels of zddp?

Min
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ic932  



Joined: 11 Feb 2005
Posts: 1104
Location: UK

PostPosted: Sun Feb 08, 2009 9:31 am    Post subject: Reply with quote

I've encountered a few ORIGINAL 924Turbo owners that have come back to the fold, (now 944 owners...boo hiss)...anyway, all have showed genuine interest in my 931 projects but both have critizied the 924Turbo for "not lasting long before re-build" (These are first time 931 owners from new). If oil technology has moved so far forward over the years than great...Snake oil, much like banana skins helps the imagination lol. Does rasta need banana skins?...well, white guys calling themselves "rasta" hmmm, know a few Jamaican lads that would........
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emoore924  



Joined: 13 Apr 2004
Posts: 2822

PostPosted: Mon Feb 09, 2009 1:08 pm    Post subject: Reply with quote

I use a zddp additive from cam-shield. They have "testimonial" type info on their website.

Here's the link:

http://www.cam-shield.com/

Ths info regarding this product initially came to me via Hagerty Insurance magazine.

No affiliation, etc., but I have had no cam/follower problems since I started using, and for +$7 an oil change, worth it as far as I'm concerned...
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ideola  



Joined: 01 Oct 2004
Posts: 15550
Location: Spring Lake MI

PostPosted: Thu Jun 04, 2009 12:36 am    Post subject: Reply with quote

Here's another ZDDP additive offered by Bill Hirsch Automotive:

hirschauto.com wrote:
After 70+ years, the EPA mandated that all domestic oil producers remove ZDDP (Zinc Dialkyl Dithio Phosphate) from all conventional and synthetic motor oil. If your engine was designed before 1989 the non-roller lifters require ZDDP to avoid premature deterioration. ZDDP also alters bearing and journal surface characteristics to prevent metal to metal contact. Under extreme conditions like a high performance motor, ZDDP reduces the tendency of parts to scuff or gall under heavy loads. Simply add ZDDP-Plus to every 4-5 quart oil change and your motor will be protected from metal to metal contact. Add one 4 ounce bottle to a 4-5 quart oil change modifier to eliminate and metal-to-metal contact.

Appliciable with all grades of conventional and synthetic motor oils. Add at time of oil change. Can be added at any time but best time is at oil change. Should only be used in motor produced in 1989 and older. Not for use in diesel motors. Not for use with OBD controlled motors.

FAQ
Can it be used in conventional and synthetic oils? YES
Will too much hurt the motor? No, do not exceed 8 oz, 2 bottles.
Can I use it in any motor? NO, 1989 and older.
Will it work in diesel? NO, it will have no effect in a diesel motor.

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Smoothie  



Joined: 01 Jan 2003
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Location: DE (the one near MD, PA, NJ)

PostPosted: Thu Jun 04, 2009 2:24 am    Post subject: Reply with quote

More discussion on the topic here - http://www.924board.org/viewtopic.php?t=24352

Somewhere along the line, after becoming aware of the situation, I read that diesel truck oils still contain higher levels of ZDDP, and switched to this - http://www.mobil.com/USA-English/Lubes/PDS/GLXXENPVLMOMobil1_Turbo_Diesel_Truck_5W-40.asp
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ideola  



Joined: 01 Oct 2004
Posts: 15550
Location: Spring Lake MI

PostPosted: Thu Jun 04, 2009 2:52 am    Post subject: Reply with quote

Some of the Mobil1 links in that other thread are now dead, but here's an interesting table from the Mobil1 site, listing the phosphorus content of their product range:
http://www.mobiloil.com/USA-English/MotorOil/Files/Mobil_1_Product_Guide.pdf

According to the chart, M1 15W50 has 1300 PPM of ZDDP, and is listed as being suitable for performance, racing and classic applications. I'm breathing a bit easier since this is what I've been running in ALL of my cars.
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Vince Ponz  



Joined: 02 Nov 2002
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Location: Florida

PostPosted: Thu Jun 04, 2009 10:09 am    Post subject: Reply with quote

As an original owner of a 77 1/2 I changed the cam in 82 and never had any problem with the car. For ten years heavy track time still no problem. Changed oil after every track event. Carbs drain gas into oil therefore I change it often. Cheap fix. Large jets
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Min  



Joined: 04 Nov 2002
Posts: 2368
Location: Vernon, British Columbia, Canada

PostPosted: Thu Jun 04, 2009 3:06 pm    Post subject: Reply with quote

turns out you can buy a zddp additive right from GM http://www.slantsix.org/articles/Modern_Engine_Oils.htm under p/n 1052367 in the US, 992869 in Canada. Your local gm dealer will have it in stock.

Min
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Arominus  



Joined: 20 Feb 2009
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Location: Colorado Springs, CO

PostPosted: Fri Jun 05, 2009 3:36 am    Post subject: Reply with quote

I've been running synthetic Rotella T 5w-40w to get my ZDDP fix, the diesel oils have not cut back on the additive.
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loosehead  



Joined: 20 Apr 2009
Posts: 10
Location: PA, west of Philly

PostPosted: Fri Jun 05, 2009 5:26 am    Post subject: Reply with quote

Eastwood is a pretty good company for the restoration folks

They carry it too:

http://www.eastwood.com/catalogsearch/result/?q=oil+additive&x=8&y=13

LH
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RC  



Joined: 25 Mar 2007
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Location: Australia

PostPosted: Sat Jun 06, 2009 4:46 am    Post subject: Reply with quote

The old debate regarding oil additives was running well prior to the days of my grandfather working on Spitfire engines during WW2. Additive manufacturers and sellers telling us their product is needed for all kinds of reasons while the oil companies inform us consumers that their oil is complete and nothing else is required and is in fact detrimental.

Although there is likely some truth in both POVs its difficult to separate the science from the hype. However there`s no escaping the fact that our engines were designed to use ZDDP to extend top end life and that modern oils meeting modern specifications simply do not contain the necessary quantity.

Additives vary from very high quality produced by specialist tribologists at major oil companies to backyard purveyors of diluted snake oil. As well as the percentage of zinc and phosphorus required to bring the total to 1400 PPM or more, what else is in the bottle and how compatible is it with the base oil being used?

A quick look at some of the additives mentioned above show its a case of hit or miss unless you know the percentage breakdown of your base oil and am prepared to do some calculations.

Cam-shield give no concentration and after 4 pages write:
Quote:
Each half-ounce of Cam-shield™ is guaranteed to deliver an additional 1600 ppm of Zinc (from ZDDP) to a quart of your favorite engine oil. If you wish to add 800 ppm of Zinc (from ZDDP) to a quart of your favorite engine oil, simply add a quarter-ounce of Cam-shield™ brand engine oil treatment to each quart that you wish to treat.


ZDDP additive from Bill Hirsch and also from Eastwood does`nt specify there or on their website. A cause for concern IMO when no specifics of ingredients are published. However reading this thread indicates that it may actually have a reasonably high percentage:
http://www.turbobuick.com/forums/general-turbo-buick-tech/226565-oil-zddp-supplement.html
Also indicates that the GM EOS had a quite low concentration but is now NLA anyway.



Theres quite a few different ZDDP additives available all over the net and ebay as well. Do your research and maths then make your own decision. Personally prefer to use a ready to run formulated complete oil with the necessary ingredients. There are many lists of oils with their relative ratios of ZDDP available, some recent and many outdated. Some reasonably priced and others exorbitantly prohibitive. Some common brands and others "boutique" and "upmarket".

More info on Pelican if you`re a keen reader:
http://forums.pelicanparts.com/showthread.php?t=367300

And more on ZDDP:
http://forums.pelicanparts.com/showthread.php?s=&threadid=289790&highlight=zddp

Oils are like religions, everyone has their favorite brand and knows they are right. Make your own informed choice. Personally have decided to try Penrite HPR30. Many other good oils are not available in Australia and have to be imported. This one is around Au$30-35 for 5L at most FLAPS. Also comes widely recommended on many Aussie car bulletin boards.
http://www.penriteoil.com.au/pis_pdfs/PI_HPR%2030.pdf
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Min  



Joined: 04 Nov 2002
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Location: Vernon, British Columbia, Canada

PostPosted: Sat Jun 06, 2009 11:37 am    Post subject: Reply with quote

RC wrote:

http://www.turbobuick.com/forums/general-turbo-buick-tech/226565-oil-zddp-supplement.html
Also indicates that the GM EOS had a quite low concentration but is now NLA anyway.


Umm, well, I can tell you first hand that the GM EOS is available. Guess how I know? ... today I went to my local gm dealer and bought some off their shelf!!!, and my local parts store has it in stock, at the front of the store near the till, must be a popular product.

I added the amount recommended by the website I posted, 8 ounces per 5 quarts of engine oil. I can tell you I'm quite satisfied with the results, my engine is quite a bit quieter, the valve train ticking almost disappeared completely. I'm suitably convinced that the engine oil I am using doesn't have a large enough quantity of zddp, and now I know why I've been having so many problems with wearing the lobes off my camshafts. I'm using Quartz Total Ineo MC3 5w30 fully synthetic fluid at the moment. Probably going to switch back to mobil 1

Min
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Power Tryp  



Joined: 16 Apr 2009
Posts: 435
Location: Calgary, Alberta

PostPosted: Wed Jun 10, 2009 1:08 pm    Post subject: Reply with quote

Looks like I'm going to have to get my leak looked after and then change to an oil that has what we need, thanks for this guys I probably would have wrecked my motor if this board wasn't on it's game like this.

Tryp
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Raceboy  



Joined: 01 Mar 2004
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Location: Estonia, Europe

PostPosted: Wed Jun 10, 2009 4:25 pm    Post subject: Reply with quote

On a race-car I use Motul 300V 20W60, on a street car usually Motul semi-synthetic.

300V is one of the best oils you can find and it has higher ZDDP levels. Here's some info: http://www.p1-performance.com/pdf/oildoc.pdf
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